I think the answer to that depends on the era you are modeling. If I read the machine-translated Japanese pages correctly, the original 10-car sets introduced in 2000 had two cars replaced with bi-level cars in 2005. Kato's 10-472 contains two single-level cars (according to one online auction site I found; Kato's website doesn't provide a picture), and thus would be appropriate for the earlier trains. Kato also made a
two-car bilevel set for the line (10-470), which isn't mentioned on the
main page for the suburban sets, but doesn't show as discontinued on the
stock list, just as "out of stock". You'd need that for the current trains.
I have one of the 10-471 sets myself, but not either of the others, so the answer to this interests me too.
Also, depending on where you model (if you are trying to be that specific), 15-car trains (10+5 sets) are likely to be more common than 10-car sets, so the second powered set (10-473) would be needed.
The
Japanese Wikipedia page for the line has some info on the E231, although I had trouble getting a useful translation of it. It seems to be mostly about where the 10 or 10+5 sets are used.